So, Sarah, to try and put it simply: on DC, the loco will always run the same direction round the track when you turn the knob the same way, irrespective of whether the loco is facing "forwards" or "backwards" - so if turning the knob to the right means the loco runs clockwise round the circuit, the loco will ALWAYS run clockwise when the knob is to the right, regardless of which way the loco is pointing on the track. If you have two locos on the track they will both run the SAME direction round the circuit, whichever way round the locos are pointing.
On DCC, turning the knob to the right sends a command to the loco's decoder that says "go forwards" - so if the loco is pointing clockwise, it will run forwards, but if it pointing anticlockwise then it will STILL run "forwards", ie: it will run anticlockwise. Turning the knob to the left tells the decoder "go backwards", so the loco will run bunker-first whichever way it is pointing on the track. If you have two DCC locos on the track pointing in opposite directions and both are given "go forwards" commands, then they will both run in OPPOSITE directions and collide!
Does that make sense, or not?
Jon.