I assume track pier is a typo and you meant track power?
Firstly, do you have a means of applying power to the track, i.e. a suitable transformer or controller? This doesn't necessary need to be a G gauge unit; a Hornby or similar one for smaller scales will do for testing.
If so, connect it to the track and use the Volts DC setting on the meter, and connect the leads to each rail.
Turn up the knob on your controller, and you will see a reading from 0 volts up to whatever the max voltage it can output.
Turn the knob the other way, or set the direction switch and you will see the polarity of the voltage change to opposite of that earlier....